Chapter 41  ·  Module 1
NSAIDs — Mechanisms, Pharmacokinetics & COX Selectivity
Arachidonic acid cascade, COX isoforms, aspirin pharmacology, and key drug interactions
Abbreviations: NSAID = nonsteroidal anti-inflammatory drug  ·  COX = cyclooxygenase  ·  PGE2 = prostaglandin E2  ·  PGI2 = prostacyclin  ·  TXA2 = thromboxane A2  ·  LOX = lipoxygenase  ·  PLA2 = phospholipase A2  ·  AERD = aspirin-exacerbated respiratory disease  ·  PPI = proton pump inhibitor
Arachidonic Acid Cascade
Membrane phospholipids
PLA2
GC block
Arachidonic acid
COX pathway
NSAID block
PGE2 — pain, fever, gastric protection, renal perfusion
PGI2 — vasodilation, inhibits platelets (endothelium)
TXA2 — vasoconstriction, promotes platelets (platelets only)
LOX pathway
Not blocked by NSAIDs
Leukotrienes — bronchoconstriction, allergic inflammation
AERD: COX block → LOX shunting → bronchoconstriction
Glucocorticoids block PLA2 via annexin A1 — suppressing both COX and LOX branches. NSAIDs block COX only.
COX-1 vs COX-2
Constitutive
COX-1
  • Gastric mucosa — cytoprotection
  • Platelets — TXA2 synthesis
  • Kidney — perfusion under stress
  • Inhibition → GI toxicity, platelet effects
Inducible (+ constitutive in endothelium)
COX-2
  • Inflamed tissue — PGE2, fever
  • Endothelium — PGI2 (anti-platelet)
  • Selective block → ↓PGI2, TXA2 intact
  • Prothrombotic state → CV risk
Aspirin — Dose-Dependent Pharmacology
Dose Range Effect Mechanism
75–325 mg/day Antiplatelet Irreversible COX-1 acetylation in platelets; endothelium regenerates COX-2 between doses
300–1,000 mg/dose Analgesia, antipyresis COX inhibition in peripheral nociceptors and hypothalamus
3,000–6,000 mg/day Anti-inflammatory Sustained systemic COX inhibition; rarely used (GI toxicity)
Toxic Tinnitus, hyperventilation, acidosis Respiratory alkalosis → metabolic acidosis; mitochondrial uncoupling
Key Aspirin Rule

Platelets are anucleate — cannot make new COX. One aspirin permanently silences TXA2 in that platelet for its 8–10 day lifespan. Daily dosing is required to suppress the renewing platelet pool.

High-Priority Drug Interactions
Ibuprofen + Aspirin
Ibuprofen blocks aspirin access to platelet COX-1 — take aspirin first, wait 30 min
NSAIDs + ACE/ARB + Diuretic
Triple whammy — additive reduction of GFR → acute kidney injury
NSAIDs + Lithium
Reduced renal lithium clearance → lithium toxicity; monitor levels
NSAIDs + Anticoagulants
Additive GI bleeding risk; use PPI if combination unavoidable
NSAIDs + SSRIs
Additive platelet dysfunction → GI bleed risk; use PPI
CYP2C9 inhibitors
Fluconazole, amiodarone → raise NSAID levels → toxicity
Key Agent Differences
Preferred in CV risk
Naproxen
  • Long half-life → sustained COX-1 inhibition
  • Partial antiplatelet effect → lowest CV risk
  • Does not block aspirin antiplatelet effect
Only selective COX-2 inhibitor (US)
Celecoxib
  • Less gastric mucosal injury than nonselective NSAIDs
  • GI benefit lost if patient also takes aspirin
  • CYP2D6 inhibitor — raises metoprolol, codeine levels
Parenteral NSAID — max 5 days
Ketorolac
  • Only NSAID for IV/IM use
  • Opioid-sparing in acute pain
  • Significant GI/renal risk limits duration
Gout, PDA closure
Indomethacin
  • Most potent nonselective COX inhibitor
  • IV formulation closes patent ductus arteriosus in neonates
  • High CNS side effects limit long-term use