Chapter 31  ·  Module 1
Estrogen & Progestin Pharmacology
Receptors · Biosynthesis · Agents · Drug Interactions
Estrogen Receptors
Estrogen Receptor Alpha
Dominant in Reproductive Tissues & Liver
  • Uterus, breast, liver, bone
  • Hypothalamic-pituitary axis (negative feedback)
  • Target for tamoxifen and raloxifene (SERMs)
  • Mediates proliferative and feminizing effects
Estrogen Receptor Beta
Modulates Estrogen Receptor Alpha Activity
  • Ovary (granulosa cells), colon, lung, central nervous system
  • Generally opposes proliferative effects of estrogen receptor alpha
  • Less targeted by available drugs
  • Basis for tissue-selective SERM pharmacology
Estrogen Biosynthesis
Theca Cell
Luteinizing hormone → androgens (androstenedione, testosterone) from cholesterol
Granulosa Cell
Follicle-stimulating hormone → aromatase (CYP19A1) → converts androgens to estrogens
Products
Androstenedione → estrone   |   Testosterone → estradiol (most potent)
Postmenopause
Ovary stops; estrone from adipose aromatization of adrenal androstenedione becomes dominant → aromatase inhibitors work here
Estrogen Route — VTE Risk Comparison
Property Oral Estradiol Ethinyl Estradiol Transdermal Estradiol
First-pass hepatic exposure Yes — high portal concentrations Yes — even higher hepatic stimulation No — bypasses portal circulation
Hepatic coagulation factors Increased Substantially increased Minimal increase
Sex hormone-binding globulin induction Moderate increase 2–4x increase Minimal
VTE risk Increased ~3–4x baseline Not increased
Preferred in VTE risk factors No No Yes
Progestin Generations — Receptor Profiles
Natural
Micronized Progesterone
  • Low oral bioavailability improved by micronization
  • Selective for progesterone receptor
  • Sedation (GABA-A metabolites)
  • Vaginal use: luteal support
1st/2nd Gen 19-Nor
Norethindrone & Levonorgestrel
  • Testosterone-derived → androgenic
  • Levonorgestrel: highest androgenic index
  • Reduces high-density lipoprotein, acne risk
  • Depot: MPA 150 mg q12 wks; fertility delay 9–10 mo
3rd Gen 19-Nor
Desogestrel / Etonogestrel
  • Reduced androgenic activity vs. levonorgestrel
  • Etonogestrel: implant (3 yr), vaginal ring
  • Better lipid profile
  • Slightly higher VTE risk than levonorgestrel
4th Gen / Spiro-Derived
Drospirenone
  • Anti-androgenic (AR blocker)
  • Anti-mineralocorticoid → K+ retention
  • Monitor K+ with ACE-I, ARBs, K+-sparing diuretics
  • Use: polycystic ovary syndrome, PMDD
Key Drug Interactions
CYP3A4 Inducers → Contraceptive Failure
Rifampin & Enzyme-Inducing Antiepileptic Drugs
  • Rifampin: most potent inducer; renders all hormonal OCs unreliable
  • Induction persists 4 weeks after last rifampin dose
  • Antiepileptic drugs that induce: carbamazepine, phenytoin, phenobarbital, oxcarbazepine
  • Safe antiepileptic drugs: valproate, levetiracetam, gabapentin, pregabalin
  • Backup: copper intrauterine device (non-hormonal)
Bidirectional Interaction
Ethinyl Estradiol + Lamotrigine
  • Ethinyl estradiol induces lamotrigine metabolism (glucuronidation)
  • Start combined oral contraceptive → lamotrigine levels fall 40–65% → seizure risk
  • Stop combined oral contraceptive → lamotrigine levels rebound → toxicity (dizziness, diplopia)
  • Progestin-only methods: no interaction (no ethinyl estradiol)
  • Preferred: progestin-only or non-hormonal method in lamotrigine-treated epilepsy
Core Rule — Oral vs. Transdermal Estrogen

Oral estrogen (ethinyl estradiol, oral estradiol, conjugated equine estrogens) → portal first-pass → hepatic coagulation factors up → VTE risk up. Transdermal estradiol → bypasses portal → no VTE risk increase. In patients with VTE risk factors: transdermal route always preferred.