Loop Diuretics and Thiazides
Mechanisms, Electrolyte Consequences, and Clinical Applications
Nephron Targets by Diuretic Class
Segment % Na Reabsorbed Transporter Diuretic Class
Proximal convoluted tubule ~65% Na-H exchanger isoform 3 + carbonic anhydrase Carbonic anhydrase inhibitors
Thick ascending limb ~25% Na-K-2Cl cotransporter (NKCC2) Loop diuretics
Distal convoluted tubule ~7% Na-Cl cotransporter (NCC) Thiazides
Collecting duct ~2% Epithelial sodium channel (ENaC) Potassium-sparing diuretics
Calcium Effects — Opposite Between Classes
Feature Loop Diuretics Thiazides
Mechanism Abolish lumen-positive potential in thick ascending limb — impair paracellular Ca reabsorption Lower intracellular Na in distal convoluted tubule — enhance TRPV5-mediated Ca entry
Calcium effect Calciuresis (urinary Ca loss) Calcium retention (hypocalciuria)
Use Hypercalcemia management Calcium nephrolithiasis prevention
Contraindication Calcium nephrolithiasis Hypercalcemia
Electrolyte Complications
Both Loop Diuretics and Thiazides
  • Hypokalemia — increased collecting duct Na delivery drives K secretion; thiazides via secondary aldosteronism
  • Hypomagnesemia — blocks paracellular Mg reabsorption (loop) or TRPM6 (thiazide)
  • Metabolic alkalosis — NHE3 upregulation, hypokalemia, secondary aldosteronism
  • Hyperuricemia — compete with urate at organic anion transporters in proximal tubule
  • Hyponatremia — thiazide-specific; impairs dilution without impairing concentration
Clinical Applications
By Drug Class
  • Loop diuretics — acute heart failure (IV furosemide), acute hypercalcemia (after IV saline)
  • Chlorthalidone — preferred thiazide for hypertension (ALLHAT data)
  • Thiazides — calcium nephrolithiasis prevention (reduce urinary Ca 30–50%)
  • Metolazone — add-on to loop diuretics in diuretic resistance (works at low GFR)
  • DOSE trial — high-dose IV furosemide (2.5x oral dose) superior in acute heart failure
Refractory Hypokalemia Rule

When potassium supplementation fails to correct hypokalemia, check and replete magnesium first. Magnesium depletion prevents suppression of collecting duct potassium secretion — the channel stays open regardless of potassium replacement. Correct the magnesium deficit, and potassium levels will respond.